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Volatile N-nitrosamines in Environment Tobacco Smoke: Sampling,Analysis, Smission Factors, and Indoor Air Exposures

Journal Article · · Environmental Science and Technology
OSTI ID:915406

A more convenient sampling and analysis method for the volatile N-nitrosamines (VNA) in ETS, using commercially available TherrnosorbIN cartridges, was developed and validated. Using the method, emission factors for the two major VNA in environmental tobacco smoke (ETS) were determined in a room-sized environmental chamber for six commercial cigarette brands, which together accounted for 62.5% of the total market in California in 1990. The average emission factors were 565 {+-} 115 and 104 {+-} 20 ng per cigarette for N-nitrosodimethylamine and N-nitrosopyrrolidine, respectively. The emission factors were used to estimate VNA exposures from ETS in a typical office building and an average residence. Indoor concentrations of N,N dimethylnitrosamine from ETS for these scenarios were less than 10% of the reported median outdoor concentration. This median outdoor concentration, however, includes many measurements made in source-dominated areas and may be considerably higher than one based on more representative sampling of outdoor air.

Research Organization:
Ernest Orlando Lawrence Berkeley NationalLaboratory, Berkeley, CA (US)
Sponsoring Organization:
USDOE Director, Office of Science
DOE Contract Number:
AC02-05CH11231
OSTI ID:
915406
Report Number(s):
LBL--37302
Journal Information:
Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 5 Vol. 30; ISSN ESTHAG; ISSN 0013-936X
Country of Publication:
United States
Language:
English