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Title: Method of solubilizing phthalocyanines and metallophthalocyanines

Patent ·
OSTI ID:875173
 [1];  [2];  [3]
  1. Bolingbrook, IL
  2. Darien, IL
  3. Downers Grove, IL
+ Show Author Affiliations

A one-step method of manufacturing soluble phthalocyanines and metallophthalocyanines, like zinc phthalocyanine, by converting a phthalocyanine or a metallophthalocyanine to a trialkylsilyl-substituted derivative is disclosed. The phthalocyanine or metallophthalocyanine is converted to a soluble trialkylsilyl-substituted derivative by interacting the phthalocyanine or metallophthalocyanine with an active metal amide, like lithium 2,2,6,6-tetramethylpiperidide, and a halotrialkylsilane, like chlorotrimethylsilane, to provide a phthalocyanine compound, like phthalocyanine monomers, dimers or polymers, metalated or unmetalated, that are soluble in organic media.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
W-31109-ENG-38
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Number(s):
H001695
Application Number:
07/531733
OSTI ID:
875173
Resource Relation:
Patent File Date: 1990 Jun 01
Country of Publication:
United States
Language:
English

References (9)

Über siliciumaromatische Verbindungen I. Trimethylsilylphtalsäuren und davon abgeleitete Farbstoffe journal January 1968
Löslichetrans-Di-1-alkinyl- und Poly-trans-ethinyl(tetraalkylphthalocyaninato)metall-IVB-Derivate journal August 1982
Preparation of a novel, soluble copper phthalocyanine with crown ether moieties journal January 1986
In situ trapping of ortho lithiated benzenes containing electrophilic directing groups journal September 1983
A copper phthalocyanine with four crown ether voids journal January 1986
Synthesis and properties of substituted (phthalocyaninato)-iron and -cobalt compounds and their pyridine adducts journal April 1984
1,4,8,11,15,18,22,25-Octa-alkyl phthalocyanines: new discotic liquid crystal materials journal January 1987
Molecular association and monolayer formation of soluble phthalocyanine compounds journal August 1984
The syntheses of mono- and disubstituted phthalocyanines using a dithioimide journal August 1987

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Related Subjects

method
solubilizing
phthalocyanines
one-step
manufacturing
soluble
metallophthalocyanines
zinc
phthalocyanine
converting
trialkylsilyl-substituted
derivative
disclosed
converted
interacting
active
metal
amide
lithium
6-tetramethylpiperidide
halotrialkylsilane
chlorotrimethylsilane
provide
compound
monomers
dimers
polymers
metalated
unmetalated
organic
media
active metal
organic media
metal amide
one-step method
step method
statutory invention registration
/999/430/