Method of solubilizing phthalocyanines and metallophthalocyanines
Abstract
A one-step method of manufacturing soluble phthalocyanines and metallophthalocyanines, like zinc phthalocyanine, by converting a phthalocyanine or a metallophthalocyanine to a trialkylsilyl-substituted derivative is disclosed. The phthalocyanine or metallophthalocyanine is converted to a soluble trialkylsilyl-substituted derivative by interacting the phthalocyanine or metallophthalocyanine with an active metal amide, like lithium 2,2,6,6-tetramethylpiperidide, and a halotrialkylsilane, like chlorotrimethylsilane, to provide a phthalocyanine compound, like phthalocyanine monomers, dimers or polymers, metalated or unmetalated, that are soluble in organic media.
- Inventors:
-
- Bolingbrook, IL
- Darien, IL
- Downers Grove, IL
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 875173
- Patent Number(s):
- H001695
- Application Number:
- 07/531733
- Assignee:
- United States of America as represented by United States (Washington, DC)
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1990 Jun 01
- Country of Publication:
- United States
- Language:
- English
- Subject:
- method; solubilizing; phthalocyanines; one-step; manufacturing; soluble; metallophthalocyanines; zinc; phthalocyanine; converting; trialkylsilyl-substituted; derivative; disclosed; converted; interacting; active; metal; amide; lithium; 6-tetramethylpiperidide; halotrialkylsilane; chlorotrimethylsilane; provide; compound; monomers; dimers; polymers; metalated; unmetalated; organic; media; active metal; organic media; metal amide; one-step method; step method; statutory invention registration; /999/430/
Citation Formats
Rathke, Jerome W., Chen, Michael J., and Fendrick, Carol M. Method of solubilizing phthalocyanines and metallophthalocyanines. United States: N. p., 1997.
Web.
Rathke, Jerome W., Chen, Michael J., & Fendrick, Carol M. Method of solubilizing phthalocyanines and metallophthalocyanines. United States.
Rathke, Jerome W., Chen, Michael J., and Fendrick, Carol M. 1997.
"Method of solubilizing phthalocyanines and metallophthalocyanines". United States. https://www.osti.gov/servlets/purl/875173.
@article{osti_875173,
title = {Method of solubilizing phthalocyanines and metallophthalocyanines},
author = {Rathke, Jerome W. and Chen, Michael J. and Fendrick, Carol M.},
abstractNote = {A one-step method of manufacturing soluble phthalocyanines and metallophthalocyanines, like zinc phthalocyanine, by converting a phthalocyanine or a metallophthalocyanine to a trialkylsilyl-substituted derivative is disclosed. The phthalocyanine or metallophthalocyanine is converted to a soluble trialkylsilyl-substituted derivative by interacting the phthalocyanine or metallophthalocyanine with an active metal amide, like lithium 2,2,6,6-tetramethylpiperidide, and a halotrialkylsilane, like chlorotrimethylsilane, to provide a phthalocyanine compound, like phthalocyanine monomers, dimers or polymers, metalated or unmetalated, that are soluble in organic media.},
doi = {},
url = {https://www.osti.gov/biblio/875173},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 1997},
month = {Wed Jan 01 00:00:00 EST 1997}
}
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