Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Alexandratos, Spiro; Shelley, Christopher A; Horwitz, E Philip; Chiarizia, Renato; Gula, Michael J; Xue, Sui; Harvey, James T

Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Patent · Mon Dec 31 23:00:00 EST 2001

OSTI ID:874912

Alexandratos, Spiro ^[1]; Shelley, Christopher A ^[1]; Horwitz, E Philip ^[2]; Chiarizia, Renato ^[3]; Gula, Michael J ^[4]; Xue, Sui ^[5]; Harvey, James T ^[2]

Knoxville, TN
Naperville, IL
Elmhurst, IL
Chicago, IL
Darien, IL

A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring, (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorus as phosphonic acid ligands, and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron(III) cations from acidic copper(II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.

View Patent

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL

DOE Contract Number:: W-31109-ENG-38

Assignee:: Arch Development Corp (Chicago, IL); The University of Tennessee Research Corp (Knoxville, TN)

Patent Number(s):: US 6488859

OSTI ID:: 874912

Country of Publication:: United States

Language:: English

References (21)

Mechanisms of polymer-supported catalysis. 1. Reaction of 1-bromooctane with aqueous sodium cyanide catalyzed by polystyrene-bound benzyltri-n-butylphosphonium ion Tomoi, M.; Ford, Warren T. Journal of the American Chemical Society, Vol. 103, Issue 13 https://doi.org/10.1021/ja00403a032	journal	July 1981
Synthesis and Ion-Complexing Properties of a Novel Polymer-Supported Reagent with Diphosphonate Ligands Alexandratos, Spiro D.; Trochimczuk, Andrzej W.; Crick, Darrell W. Macromolecules, Vol. 29, Issue 3 https://doi.org/10.1021/ma950943u	journal	January 1996
Radical copolymerization of monovinyl derivatives of phosphorus Levin, Ya. A.; Fridman, G. B.; Ivanov, B. Ye. Polymer Science U.S.S.R., Vol. 17, Issue 4 https://doi.org/10.1016/0032-3950(75)90272-5	journal	January 1975
Chelating resins supporting dithiocarbamate and methylthiourea groups in adsorption of heavy metal ions Lezzi, A.; Cobianco, S. Journal of Applied Polymer Science, Vol. 54, Issue 7 https://doi.org/10.1002/app.1994.070540708	journal	November 1994
Uptake of Metal ions by a new Chelating Ion-Exchange Resin. part 2: acid Dependencies of Transition and Post-Transition Metal ions Chiarizia, R.; Horwitz, E. P.; Gatrone, R. C. Solvent Extraction and Ion Exchange, Vol. 11, Issue 5 https://doi.org/10.1080/07366299308918196	journal	October 1993
Synthesis of aza macrocycles by nucleophilic ring closure with cesium tosylamides Vriesema, Bindert K.; Buter, Jan; Kellogg, Richard M. The Journal of Organic Chemistry, Vol. 49, Issue 1 https://doi.org/10.1021/jo00175a022	journal	January 1984
Synthesis and characterization of oxime resin of poly(4-viny1, 2′-carboxybenzophenone) and its metal polychelates Kamble, K. j.; Patkar, D. N. Journal of Applied Polymer Science, Vol. 56, Issue 11 https://doi.org/10.1002/app.1995.070561114	journal	June 1995
Synthesis of phosphorus-containing wofatit cation exchangers and their affinity toward selected cations Bogoczek, Romuald; Surowiec, Joanna Journal of Applied Polymer Science, Vol. 26, Issue 12 https://doi.org/10.1002/app.1981.070261218	journal	December 1981
Uptake of Metal ions by a new Chelating Ion-Exchange Resin. part 1: acid Dependencies of Actinide Ions* Horwitz**, E. P.; Chiarizia, R.; Diamond, H. Solvent Extraction and Ion Exchange, Vol. 11, Issue 5 https://doi.org/10.1080/07366299308918195	journal	October 1993
Uptake of Metal ions by a new Chelating Ion-Exchange Resin. part 4 : Kinetics Chiarizia, R.; Horwitz, E. P.; Alexandratos, S. D. Solvent Extraction and Ion Exchange, Vol. 12, Issue 1 https://doi.org/10.1080/07366299408918209	journal	January 1994
Enhanced ionic recognition by polymer-supported reagents: synthesis and characterization of ion-exchange/precipitation resins Alexandratos, Spiro D.; Bates, Marie E. Macromolecules, Vol. 21, Issue 10 https://doi.org/10.1021/ma00188a001	journal	October 1988
Electron-transfer polymers (oxidation-reduction polymers) Cassidy, Harold G. Journal of Polymer Science: Macromolecular Reviews, Vol. 6, Issue 1 https://doi.org/10.1002/pol.1972.230060101	journal	January 1972
Metal uptake by didentate and tridentate pyrazole-containing ligands immobilized onto poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) van Berkel, P. M.; Verweij, P. D.; Driessen, W. L. European Polymer Journal, Vol. 28, Issue 7 https://doi.org/10.1016/0014-3057(92)90078-G	journal	July 1992
Application of a macroporous resin containing imidazoline groups to preconcentration and separation of gold, platinum and palladium prior to ICP-AES determination Su, Z. Talanta, Vol. 42, Issue 8 https://doi.org/10.1016/0039-9140(95)01553-N	journal	August 1995
Synthesis, properties and applications of silica-immobilized 8-quinolinol Lan, Chi-Ren; Yang, Mo-Hsiung Analytica Chimica Acta, Vol. 287, Issue 1-2 https://doi.org/10.1016/0003-2670(94)85107-7	journal	March 1994
Adsorption of metal ions on polyaminated highly porous chitosan chelating resin Kawamura, Yoshihide; Mitsuhashi, Masaki; Tanibe, Hiroaki Industrial & Engineering Chemistry Research, Vol. 32, Issue 2 https://doi.org/10.1021/ie00014a015	journal	February 1993
A Mechanism for Enhancing Ionic Accessibility into Selective ion Exchange Resins Alexandratos, Spiro D.; Shelley, Christopher A.; Philip Horwitz, E. Solvent Extraction and Ion Exchange, Vol. 16, Issue 4 https://doi.org/10.1080/07366299808934562	journal	July 1998
Dual-mechanism bifunctional polymers: polystyrene-based ion-exchange/redox resins Alexandratos, Spiro D.; Wilson, David L. Macromolecules, Vol. 19, Issue 2 https://doi.org/10.1021/ma00156a006	journal	March 1986
Bifunctionality as a Means of Enhancing Complexation Kinetics in Selective Ion Exchange Resins Alexandratos, Spiro D.; Hussain, Latiff A. Industrial & Engineering Chemistry Research, Vol. 34, Issue 1 https://doi.org/10.1021/ie00040a026	journal	January 1995
Poly(vinylbenzo macrocyclic polyethers). Synthesis and cation binding properties of 12-crown-4 derivatives Buchanan, G. W.; Denike, J. K. Canadian Journal of Chemistry, Vol. 69, Issue 4 https://doi.org/10.1139/v91-105	journal	April 1991
Synthesis of bifunctional ion-exchange resins through the Arbusov reaction: Effect on selectivity and kinetics Trochimczuk, Andrzej W.; Alexandratos, Spiro D. Journal of Applied Polymer Science, Vol. 52, Issue 9 https://doi.org/10.1002/app.1994.070520912	journal	May 1994

Similar Records

Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Patent · Sun Dec 31 23:00:00 EST 2000 · OSTI ID:873738

Removal of metal pollutants (Cd(II) and Cr(III)) from phosphoric acid solutions by chelating resins containing phosphonic or diphosphonic groups

Journal Article · Mon Jun 01 00:00:00 EDT 1998 · Industrial and Engineering Chemistry Research · OSTI ID:651199

Grafted methylenediphosphonate ion exchange resins

Patent · Tue Dec 31 23:00:00 EST 1996 · OSTI ID:870894

Related Subjects

/210/
31
acid
acidic
amount
aqueous
aqueous solution
bifunctional
cation-containing
cations
comprised
contains
contemplated
copperii
cross-linked
disclosed
exchange
exchange resin
ii
iii
ironiii
ligand
ligands
linked
metal
millimoles
mmolg
monomers
monophosphonicsulfonic
phenyl
phosphonic
phosphorus
polymerized
polyvalent
process
ratio
removing
resin
resins
ring-containing
solution
solutions
sufficient
sufficient amount
sulfonic
utilize
water-insoluble

Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Citation Formats

References (21)

Similar Records

Related Subjects