Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Alexandratos, Spiro; Shelley, Christopher A; Horwitz, E Philip; Chiarizia, Renato; Gula, Michael J; Xue, Sui; Harvey, James T

Title: Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Patent · Tue Jan 01 00:00:00 EST 2002

OSTI ID:874912

Alexandratos, Spiro ^[1]; Shelley, Christopher A ^[1]; Horwitz, E Philip ^[2]; Chiarizia, Renato ^[3]; Gula, Michael J ^[4]; Xue, Sui ^[5]; Harvey, James T ^[2]

Knoxville, TN
Naperville, IL
Elmhurst, IL
Chicago, IL
Darien, IL

A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring, (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorus as phosphonic acid ligands, and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron(III) cations from acidic copper(II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

DOE Contract Number:: W-31109-ENG-38

Assignee:: Arch Development Corp (Chicago, IL); The University of Tennessee Research Corp (Knoxville, TN)

Patent Number(s):: US 6488859

OSTI ID:: 874912

Country of Publication:: United States

Language:: English

References (21)

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bifunctional
phenyl
monophosphonicsulfonic
acid
exchange
resin
process
cross-linked
water-insoluble
comprised
polymerized
monomers
disclosed
contemplated
contains
ring-containing
phosphonic
ligand
linked
ii
millimoles
mmolg
phosphorus
ligands
iii
sufficient
amount
sulfonic
ratio
31
removing
polyvalent
metal
cations
aqueous
solution
ironiii
acidic
copperii
cation-containing
solutions
utilize
resins
aqueous solution
exchange resin
sufficient amount
/210/

Title: Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

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References (21)

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