Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Alexandratos, Spiro; Shelley, Christopher A; Horwitz, E Philip; Chiarizia, Renato

Title: Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

Patent · Mon Jan 01 00:00:00 EST 2001

OSTI ID:873738

Alexandratos, Spiro ^[1]; Shelley, Christopher A ^[1]; Horwitz, E Philip ^[2]; Chiarizia, Renato ^[3]

Knoxville, TN
Naperville, IL
Elmhurst, IL

A cross-linked water-insoluble ion exchange resin comprised of polymerized monomers having a phenyl ring is disclosed. A contemplated resin contains (i) polymerized phenyl ring-containing monomers having a phosphonic acid ligand linked to the phenyl ring, (ii) about 2 to about 5 millimoles per gram (mmol/g) of phosphorus as phosphonic acid ligands, and (iii) a sufficient amount of a sulfonic acid ligand such that the ratio of mmol/g of phosphonic acid to mmol/g sulfonic acid is up to 3:1. A process for removing polyvalent metal cations from aqueous solution, and a process for removing iron(III) cations from acidic copper(II) cation-containing solutions that utilize the contemplated resin or other resins are disclosed.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

DOE Contract Number:: W-31109-ENG-38

Assignee:: Arch Development Corporation (Chicago, IL)

Patent Number(s):: US 6232353

OSTI ID:: 873738

Country of Publication:: United States

Language:: English

References (20)

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bifunctional
phenyl
monophosphonic
sulfonic
acid
exchange
resin
process
cross-linked
water-insoluble
comprised
polymerized
monomers
disclosed
contemplated
contains
ring-containing
phosphonic
ligand
linked
ii
millimoles
mmol
phosphorus
ligands
iii
sufficient
amount
ratio
removing
polyvalent
metal
cations
aqueous
solution
iron
acidic
copper
cation-containing
solutions
utilize
resins
metal cations
sufficient amount
sulfonic acid
exchange resin
aqueous solution
ion-containing solution
phosphonic acid
polyvalent metal
metal cation
containing solution
ligand linked
/521/210/423/526/

Title: Bifunctional phenyl monophosphonic/sulfonic acid ion exchange resin and process for using the same

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References (20)

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