Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Method for making surfactant-templated thin films

Patent ·
OSTI ID:874427
 [1];  [2];  [1]
  1. Albuquerque, NM
  2. San Jose, CA
+ Show Author Affiliations

An evaporation-induced self-assembly method to prepare a porous, surfactant-templated, thin film by mixing a silica sol, a solvent, a surfactant, and an interstitial compound, evaporating a portion of the solvent to form a liquid, crystalline thin film mesophase material, and then removal of the surfactant template. Coating onto a substrate produces a thin film with the interstitial compound either covalently bonded to the internal surfaces of the ordered or disordered mesostructure framework or physically entrapped within the ordered or disordered mesostructured framework. Particles can be formed by aerosol processing or spray drying rather than coating onto a substrate. The selection of the interstitial compound provides a means for developing thin films for applications including membranes, sensors, low dielectric constant films, photonic materials and optical hosts.

Research Organization:
SANDIA CORP
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Number(s):
US 6387453
OSTI ID:
874427
Country of Publication:
United States
Language:
English

References (6)

Functionalized Monolayers on Ordered Mesoporous Supports journal May 1997
Synthesis and Characterization of a Reactive Vinyl-Functionalized MCM-41:  Probing the Internal Pore Structure by a Bromination Reaction journal April 1997
Continuous self-assembly of organic–inorganic nanocomposite coatings that mimic nacre journal July 1998
Synthesis and characterization of ordered organo–silica–surfactant mesophases with functionalized MCM-41-type architecture journal January 1997
Synthesis of hybrid inorganic–organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors journal January 1996
The critical micelle concentration of sodium dodecyl sulfate-bivalent metal dodecyl sulfate mixtures in aqueous solutions journal January 1974

Similar Records

Method for making surfactant-templated thin films
Patent · Tue Aug 31 00:00:00 EDT 2010 · OSTI ID:1176713
Method for making surfactant-templated, high-porosity thin films
Patent · Sun Dec 31 23:00:00 EST 2000 · OSTI ID:873911
The Effects of Template and Precursor Chemistry on Structure and Properties of Mesoporous TiO2 Thin Films
Journal Article · Tue Oct 12 00:00:00 EDT 2004 · Langmuir · OSTI ID:15010690

Related Subjects

/427/
aerosol
applications
bonded
coating
compound
constant
covalently
crystalline
developing
dielectric
disordered
drying
entrapped
evaporating
evaporation-induced
film
films
form
formed
framework
hosts
including
internal
interstitial
liquid
material
materials
means
membranes
mesophase
mesostructure
mesostructured
method
mixing
optical
particles
phase material
photonic
physically
porous
portion
prepare
processing
produces
provides
removal
selection
self-assembly
sensors
silica
silica sol
sol
solvent
spray
substrate
surfaces
surfactant
surfactant-templated
template