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Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains

Patent ·
OSTI ID:871648
 [1];  [2];  [3]
  1. Glen Mills, PA
  2. Wallingford, PA
  3. Boothwyn, PA
+ Show Author Affiliations

Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.

Research Organization:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
DOE Contract Number:
FC21-90MC26029
Assignee:
Sun Company, Inc. (R&M) (Philadelphia, PA)
Patent Number(s):
US 5770728
OSTI ID:
871648
Country of Publication:
United States
Language:
English

References (7)

Halogen Substituent Effects on the Catalytic Activity of Iron Porphyrin Complexes for the Decomposition of tert-Butyl Hydroperoxide journal May 1993
Facile Synthesis of meso-Tetrakis(perfluoroalkyl)porphyrins: Spectroscopic Properties and X-ray Crystal Structure of Highly Electron-Deficient 5,10,15,20-Tetrakis(heptafluoropropyl)porphyrin journal November 1994
Investigation of the synthesis of ortho-substituted tetraphenylporphyrins journal February 1989
On the preparation of metalloporphyrins journal July 1970
Halogen substituent effects on the catalytic activity of iron porphyrin complexes for selective air-oxidation of alkanes in the liquid phase journal September 1989
Porphyrins. VII. The synthesis of porphyrins by the Rothemund reaction journal January 1964
Selective low temperature hydroxylation of isobutane by molecular oxygen catalyzed by an iron perhaloporphyrin complex journal January 1991

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Related Subjects

/999/
alkane
alkane oxidation
alkanes
atoms
carbon
carbon atom
carbon atoms
catalysts
chains
complexes
contain
decomposition
effective
effective catalyst
effective catalysts
found
haloalkyl
highly
highly effective
hydroperoxides
meso-haloalkylporphyrins
metal
metal complex
metal complexes
oxidation
porphyrins
transition
transition metal