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Porphyrins and metal complexes thereof having haloalkyl side chains

Patent ·
OSTI ID:870850
 [1];  [2];  [3]
  1. Glen Mills, PA
  2. Wallingford, PA
  3. Boothwyn, PA
+ Show Author Affiliations
Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.
Research Organization:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
DOE Contract Number:
FC21-90MC26029
Assignee:
Sun Company, Inc. (R&M) (Philadelphia, PA)
Patent Number(s):
US 5608054
OSTI ID:
870850
Country of Publication:
United States
Language:
English

References (1)

Facile Synthesis of meso-Tetrakis(perfluoroalkyl)porphyrins: Spectroscopic Properties and X-ray Crystal Structure of Highly Electron-Deficient 5,10,15,20-Tetrakis(heptafluoropropyl)porphyrin journal November 1994

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alkanes
atoms
carbon
carbon atom
carbon atoms
catalysts
chains
complexes
contain
decomposition
effective
effective catalyst
effective catalysts
found
haloalkyl
highly
highly effective
hydroperoxides
meso-haloalkylporphyrins
metal
metal complex
metal complexes
oxidation
porphyrins
transition
transition metal