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Process for making propenyl ethers and photopolymerizable compositions containing them

Patent ·
OSTI ID:870264

Propenyl ether monomers of formula V wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Research Organization:
Rensselaer Polytechnic Inst., Troy, NY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-91ER12117
Assignee:
Rensselaer Polytechnic Institute (Troy, NY)
Patent Number(s):
5,486,545
Application Number:
08/232,507
OSTI ID:
870264
Country of Publication:
United States
Language:
English

References (7)

Synthesis, characterization, and properties of novel aromatic bispropenyl ethers journal September 1984
Structure and reactivity α,β-unsaturated ethers. II. Cationic copolymerizations of propenyl isobutyl ether journal April 1968
New synthesis of aryl-substituted sulfonium salts and their applications in photoinitiated cationic polymerization journal November 1990
Structure and reactivity of α,β-unsaturated ethers. III. Cationic copolymerizations of alkenyl alkyl ethers journal April 1968
Cationic polymerization of α,β-disubstituted olefins. Part II. Cationic polymerization of propenyl N-butyl ether journal July 1967
Structure and reactivity of α,β-unsaturated ethers. XIII. Cationic copolymerization and acid-catalyzed hydrolysis of 1,2-dialkoxyethylenes journal March 1971
Structure and reactivity of α,β-unsaturated ethers. VII. Electronic effects of the β-methyl substitution on the cationic polymerizabilities of alkyl vinyl ethers journal November 1969

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