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Metal complexes of substituted Gable porphyrins as oxidation catalysts

Patent ·
OSTI ID:870233
 [1];  [2]
  1. Wallingford, PA
  2. Murrysville, PA
+ Show Author Affiliations
Transition metal complexes of Gable porphyrins having two porphyrin rings connected through a linking group, and having on the porphyrin rings electron-withdrawing groups, such as halogen, nitro or cyano. These complexes are useful as catalysts for the oxidation of organic compounds, e.g. alkanes.
Research Organization:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
DOE Contract Number:
FC21-90MC26029
Assignee:
Sun Company, Inc. (R&M) (Philadelphia, PA)
Patent Number(s):
US 5480986
OSTI ID:
870233
Country of Publication:
United States
Language:
English

References (3)

Cooperative dioxygen binding by cobalt(II) gable porphyrin in homogeneous solution journal May 1983
Synthesis and chromophoric interactions of an ‘ortho-gable-porphyrin.’ a novel tetraphenylporphyrin dimer journal January 1989
Gable-porphyrin as a cytochrome-c3 model journal January 1982

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Related Subjects

/999/
alkanes
catalysts
complexes
compounds
connected
cyano
electron-withdrawing
gable
gable porphyrins
halogen
linking
metal
metal complex
metal complexes
nitro
organic
organic compound
organic compounds
oxidation
oxidation catalyst
oxidation catalysts
porphyrin
porphyrin rings
porphyrins
rings
substituted
transition
transition metal
useful