Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation
Patent
·
OSTI ID:869710
- Wallingford, PA
New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.
- Research Organization:
- Sun Refining and Marketing Co., Marcus Hook, PA (United States)
- DOE Contract Number:
- FC21-90MC26029
- Assignee:
- Sun Company, Inc. (R&M) (Philadelphia, PA)
- Patent Number(s):
- US 5382662
- OSTI ID:
- 869710
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
-pyrrolic
-pyrrolic positions
/999/
alkane
alkane oxidation
alkanes
attached
attached thereto
beta
catalysts
chromium
cobalt
complexes
compositions
comprising
comprising cyano-substituted
copper
cyano
cyano-
cyano-substituted
cyano-substituted metal
iron
manganese
matter
matter comprising
meso
metal
metal complex
metal complexes
oxidation
polycyanometallo-porphyrins
porphyrin
porphyrins
positions
ruthenium
thereto
-pyrrolic positions
/999/
alkane
alkane oxidation
alkanes
attached
attached thereto
beta
catalysts
chromium
cobalt
complexes
compositions
comprising
comprising cyano-substituted
copper
cyano
cyano-
cyano-substituted
cyano-substituted metal
iron
manganese
matter
matter comprising
meso
metal
metal complex
metal complexes
oxidation
polycyanometallo-porphyrins
porphyrin
porphyrins
positions
ruthenium
thereto