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Nitrated metalloporphyrins as catalysts for alkane oxidation

Patent ·
OSTI ID:869130
 [1]
  1. Wallingford, PA
+ Show Author Affiliations

Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or .beta.-pyrrolic positions.

Research Organization:
Sun Refining and Marketing Co., Marcus Hook, PA (United States)
DOE Contract Number:
FC21-90MC26029
Assignee:
Sun Company, Inc. (R&M) (Philadelphia, PA)
Patent Number(s):
US 5280115
OSTI ID:
869130
Country of Publication:
United States
Language:
English

References (7)

Nitrooctaethylporphyrins: synthesis, optical and redox properties journal February 1985
Control of reactivity at the porphyrin periphery by metal ion co-ordination: a general method for specific nitration at the β-pyrrolic position of 5,10,15,20-tetra-arylporphyrins journal January 1984
The reactions of magnesium octaethylporphyrin and its Π-cations with nitrogen dioxide and nitrite. journal June 1976
A new and highly efficient synthesis of hydroxyporphyrins journal January 1987
Electron spin resonance evidence for dimer formation in high spin iron(III)-octaethylporphyrin and iron(III)-meso-nitro-octaethylporphyrin in solution journal January 1978
The meso Reactivity of Porphyrins and Related Compounds. I. Nitration journal August 1965
Efficient peripheral functionalization of porphyrins journal January 1982

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Related Subjects

-pyrrolic
-pyrrolic positions
/999/
alkane
alkane oxidation
alkanes
attached
attached thereto
beta
catalysts
chromium
cobalt
complexes
compositions
comprising
copper
iron
manganese
matter
matter comprising
meso
metal
metal complex
metal complexes
metalloporphyrins
nitrated
nitrated metalloporphyrins
nitro
nitro-substituted
oxidation
porphyrin
porphyrins
positions
ruthenium
thereto