Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture
Patent
·
OSTI ID:866228
- Monroeville, PA
- Pittsburgh, PA
Synthesis gas containing CO and H.sub.2 is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6-20% by weight, and thoria at 0.5-3.9% by weight. The contacting occurs at a temperature of 250.degree.-300.degree. C., and a pressure of 10-30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.
- Research Organization:
- Pittsburgh Energy Technology Center
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Number(s):
- US 4659743
- OSTI ID:
- 866228
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
-300
/518/502/
10
10-30
250
5-3
6-20
80
aromatics
atmospheres
boiling
boiling range
bringing
carbon product
catalyst
cobalt
conditions
contact
contacting
containing
converted
converting
converting synthesis
degree
form
gas
gas containing
gasoline
gasoline boiling
heterogeneous
heterogeneous catalyst
high-octane
hydrocarbon
hydrocarbon liquid
hydrocarbon product
including
liquid
liquid hydrocarbon
major
major portion
mixture
molecular
molecular sieve
occurs
octane
physical
physical mixture
portion
pressure
process
product
range
selected
sieve
synthesis
synthesis gas
temperature
thoria
weight
zeolite
/518/502/
10
10-30
250
5-3
6-20
80
aromatics
atmospheres
boiling
boiling range
bringing
carbon product
catalyst
cobalt
conditions
contact
contacting
containing
converted
converting
converting synthesis
degree
form
gas
gas containing
gasoline
gasoline boiling
heterogeneous
heterogeneous catalyst
high-octane
hydrocarbon
hydrocarbon liquid
hydrocarbon product
including
liquid
liquid hydrocarbon
major
major portion
mixture
molecular
molecular sieve
occurs
octane
physical
physical mixture
portion
pressure
process
product
range
selected
sieve
synthesis
synthesis gas
temperature
thoria
weight
zeolite