Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture
Patent
·
OSTI ID:7258443
Synthesis gas containing CO and H[sub 2] is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6--20% by weight, and thoria at 0.5--3.9% by weight. The contacting occurs at a temperature of 250--300 C, and a pressure of 10--30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.
- Assignee:
- Dept. of Energy, Washington, DC (United States)
- Patent Number(s):
- A; US 4659743
- Application Number:
- PPN: US 6-542558
- OSTI ID:
- 7258443
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
10 SYNTHETIC FUELS
100200* -- Synthetic Fuels-- Production-- (1990-)
ACTINIDE COMPOUNDS
ANTIKNOCK RATINGS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
COBALT
ELEMENTS
FLUIDS
FUELS
GASES
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
LOADING RATE
MATERIALS
METALS
METHANATION
MINERALS
OXIDES
OXYGEN COMPOUNDS
SILICATE MINERALS
SYNTHESIS
SYNTHESIS GAS
SYNTHETIC FUELS
THORIUM COMPOUNDS
THORIUM OXIDES
TRANSITION ELEMENTS
ZEOLITES
100200* -- Synthetic Fuels-- Production-- (1990-)
ACTINIDE COMPOUNDS
ANTIKNOCK RATINGS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
COBALT
ELEMENTS
FLUIDS
FUELS
GASES
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
LOADING RATE
MATERIALS
METALS
METHANATION
MINERALS
OXIDES
OXYGEN COMPOUNDS
SILICATE MINERALS
SYNTHESIS
SYNTHESIS GAS
SYNTHETIC FUELS
THORIUM COMPOUNDS
THORIUM OXIDES
TRANSITION ELEMENTS
ZEOLITES