Process for the regeneration of metallic catalysts
Patent
·
OSTI ID:863853
- Newark, DE
A method for the regeneration of metallic hydrogenation catalysts from the class consisting of Ni, Rh, Pd, Ir, Pt and Ru poisoned with sulfur, with or without accompanying carbon deposition, comprising subjecting the catalyst to exposure to oxygen gas in a concentration of about 1-10 ppm. intermixed with an inert gas of the group consisting of He, A, Xe, Kr, N.sub.2 and air substantially free of oxygen to an extent such that the total oxygen molecule throughout is in the range of about 10 to 20 times that of the hydrogen sulfide molecular exposure producing the catalyst poisoning while maintaining the temperature in the range of about 300.degree. to 500.degree. C.
- Research Organization:
- Delaware Univ., Newark (USA)
- Assignee:
- University of Delaware (Newark, DE)
- Patent Number(s):
- US 4260518
- OSTI ID:
- 863853
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
/502/518/
1-10
10
20
300
500
accompanying
air
carbon
carbon deposition
catalyst
catalysts
comprising
comprising subjecting
concentration
consisting
degree
deposition
exposure
extent
free
gas
hydrogen
hydrogen sulfide
hydrogenation
hydrogenation catalyst
inert
inert gas
intermixed
kr
maintaining
metallic
metallic catalyst
metallic catalysts
method
molecular
molecule
oxygen
oxygen gas
pd
poisoned
poisoning
ppm
process
producing
range
regeneration
ru
subjecting
substantially
substantially free
sulfide
sulfur
temperature
throughout
times
total
xe
1-10
10
20
300
500
accompanying
air
carbon
carbon deposition
catalyst
catalysts
comprising
comprising subjecting
concentration
consisting
degree
deposition
exposure
extent
free
gas
hydrogen
hydrogen sulfide
hydrogenation
hydrogenation catalyst
inert
inert gas
intermixed
kr
maintaining
metallic
metallic catalyst
metallic catalysts
method
molecular
molecule
oxygen
oxygen gas
pd
poisoned
poisoning
ppm
process
producing
range
regeneration
ru
subjecting
substantially
substantially free
sulfide
sulfur
temperature
throughout
times
total
xe