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Photoemission Study of the Rare Earth Intermetallic Compounds: RNi2Ge2 (R=Eu, Gd)

Thesis/Dissertation ·
DOI:https://doi.org/10.2172/835299· OSTI ID:835299
 [1]
  1. Iowa State Univ., Ames, IA (United States)

EuNi2Ge2 and GdNi2Ge2 are two members of the RT2X2 (R = rare earth, T = transition metal and X = Si, Ge) family of intermetallic compounds, which has been studied since the early 1980s. These ternary rare-earth intermetallic compounds with the tetragonal ThCr2Si2 structure are known for their wide variety of magnetic properties, Extensive studies of the RT2X2 series can be found in Refs [ 1,2,3]. The magnetic properties of the rare-earth nickel germanides RNi2Ge2 were recently studied in more detail [4]. The purpose of this dissertation is to investigate the electronic structure (both valence band and shallow core levels) of single crystals of EuNi2Ge2 and GdNi2Ge2 and to check the assumptions that the f electrons are non-interacting and, consequently, the rigid-band model for these crystals would work [11], using synchrotron radiation because, to the best of our knowledge, no photoemission measurements on those have been reported. Photoemission spectroscopy has been widely used to study the detailed electronic structure of metals and alloys, and especially angle-resolved photoemission spectroscopy (ARPES) has proven to be a powerful technique for investigating Fermi surfaces (FSs) of single-crystal compounds.

Research Organization:
Ames Lab., Ames, IA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
W-7405-ENG-82
OSTI ID:
835299
Report Number(s):
IS--T 1936
Country of Publication:
United States
Language:
English