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Fate of SO{sub 2} During Plasma Treatment of Diesel Engine Exhaust

Conference ·
OSTI ID:790353
Several catalytic aftertreatment technologies rely on the conversion of NO to NO{sub 2} to achieve efficient reduction of NO{sub x} and particulates in diesel engine exhaust. These technologies require low sulfur fuel because the catalyst component that is active in converting NO to NO{sub 2} is also active in converting SO{sub 2} to SO{sub 3}. A non-thermal plasma can be used for the selective partial oxidation of NO to NO{sub 2} in the gas-phase under diesel engine exhaust conditions. This paper discusses how a non-thermal plasma can efficiently oxidize NO to NO{sub 2} without oxidizing SO{sub 2} to SO{sub 3}. It is shown that the presence of hydrocarbons in the plasma is essential for enhancing the selective partial oxidation of NO and suppressing the oxidation of SO{sub 2}.
Research Organization:
Lawrence Livermore National Lab., CA (US)
Sponsoring Organization:
USDOE Office of Defense Programs (DP) (US)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
790353
Report Number(s):
UCRL-JC-136269
Country of Publication:
United States
Language:
English