Complexes of oxoperoxovanadium(V) with a pyridine-2-carboxylate ion and o-phenanthroline: Specific features of coordination of bidentate chelate ligands in vanadium(V) oxo peroxo compounds

Journal Article · Fri Oct 01 00:00:00 EDT 1993 · Russian Journal of Coordination Chemistry

OSTI ID:75781

Borzunov, V K; Sergienko, V S; Porai-Koshits, M A ^[1]

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1. Kurnakov Institute of General and Inorganic Chemistry, Moscow (Russian Federation)

For studying the mutual influence of ligands in pseudooctahedral oxo peroxo complexes of vanadium(V), three compounds are synthesized: PPh{sub 4}[VO(O{sub 2})Pic{sub 2}]{center_dot}2.5H{sub 2}O (I), [VO(O{sub 2})PicPhen]{center_dot}0.5CH{sub 2}Cl{sub 2} (II), and [VO(O{sub 2})Phen(H{sub 2}O){sub 2}]Cl{center_dot}0.38H{sub 2}O (III). Comparison of complexes I - III with other investigated oxo monoperoxo compounds of vanadium(V) with bidentate ligands serves as an example for discussing the specific features of the position of the latter in the inner sphere of complexes of this type.

• OSTI ID: 75781
• Journal Information: Russian Journal of Coordination Chemistry, Journal Name: Russian Journal of Coordination Chemistry Journal Issue: 10 Vol. 19; ISSN RJCCEY
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
CARBOXYLIC ACIDS
CHELATES
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
MOLECULAR STRUCTURE
PEROXIDES
PHENANTHROLINES
VANADIUM COMPLEXES