Interaction of uranyl molybdate with the Na{sub 2}MoO{sub 4}-Na{sub 2}Mo{sub 2}O{sub 4} melt
Journal Article
·
· Russian Journal of Electrochemistry
OSTI ID:75644
- Institute of High Temperature Electrochemistry, Ekaterinburg (Russian Federation)
Behavior of uranyl molybdate in molten Na{sub 2}MoO{sub 4}-Na{sub 2}Mo{sub 2}O{sub 7} salt mixture at 1073 K in air was studied using cyclic linear voltammetry and potentiometric titration techniques. Uranyl complexes of two types ([UO{sub 2}(MoO{sub 4}){sub 2}]{sup 2{minus}} and UO{sub 3}MoO{sub 4}{sup 2{minus}}) were shown to be formed in the solution upon the addition of UO{sub 2}MoO{sub 4}. The composition of a cathodic product was found to be determined by the molar ratio of these two complexes in the melt.
- OSTI ID:
- 75644
- Journal Information:
- Russian Journal of Electrochemistry, Journal Name: Russian Journal of Electrochemistry Journal Issue: 6 Vol. 30; ISSN RJELE3
- Country of Publication:
- United States
- Language:
- English
Similar Records
Electrocrystallization of UO{sub 2{+-}X} from K{sub 2}MoO{sub 4}-K{sub 2}Mo{sub 2}O{sub 7}-UO{sub 2}MoO{sub 4} molten salt
Cathodic reactions in electrolysis of an Na{sub 2}MoO{sub 4}-UO{sub 2}MoO{sub 4} melt
From {sub {infinity}}{sup 1}[(UO{sub 2}){sub 2}O(MoO{sub 4}){sub 4}]{sup 6-} to {sub {infinity}}{sup 1}[(UO{sub 2}){sub 2}(MoO{sub 4}){sub 3}(MoO{sub 5})]{sup 6-} infinite chains in A{sub 6}U{sub 2}Mo{sub 4}O{sub 21} (A=Na, K, Rb, Cs) compounds: Synthesis and crystal structure of Cs{sub 6}[(UO{sub 2}){sub 2}(MoO{sub 4}){sub 3}(MoO{sub 5})]
Journal Article
·
Sat Dec 31 23:00:00 EST 1994
· Radiochemistry
·
OSTI ID:28608
Cathodic reactions in electrolysis of an Na{sub 2}MoO{sub 4}-UO{sub 2}MoO{sub 4} melt
Journal Article
·
Sat Jul 01 00:00:00 EDT 1995
· Radiochemistry
·
OSTI ID:160272
From {sub {infinity}}{sup 1}[(UO{sub 2}){sub 2}O(MoO{sub 4}){sub 4}]{sup 6-} to {sub {infinity}}{sup 1}[(UO{sub 2}){sub 2}(MoO{sub 4}){sub 3}(MoO{sub 5})]{sup 6-} infinite chains in A{sub 6}U{sub 2}Mo{sub 4}O{sub 21} (A=Na, K, Rb, Cs) compounds: Synthesis and crystal structure of Cs{sub 6}[(UO{sub 2}){sub 2}(MoO{sub 4}){sub 3}(MoO{sub 5})]
Journal Article
·
Sun May 15 00:00:00 EDT 2011
· Journal of Solid State Chemistry
·
OSTI ID:21494285