Nonplanarity and the protonation behavior of porphyrins
Journal Article
·
· Chemical Communications
OSTI ID:753381
- Sandia National Laboratories
{sup 1}H NMR studies of the protonation of highly nonplanar porphyrins with strong acids reveal the presence of the previously elusive monocation, and show that its stability can be related to the amount of saddle distortion induced by protonation; the amount of saddle distortion for a porphyrin dication is also found to correlate well with the rate of intermolecular proton transfer.
- Research Organization:
- Sandia National Labs., Albuquerque, NM (US); Sandia National Labs., Livermore, CA (US)
- Sponsoring Organization:
- US Department of Energy (US)
- DOE Contract Number:
- AC04-94AL85000
- OSTI ID:
- 753381
- Report Number(s):
- SAND2000-0732J
- Journal Information:
- Chemical Communications, Journal Name: Chemical Communications
- Country of Publication:
- United States
- Language:
- English
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