Characterization of the methylene /sup 13/C chemical shift tensor in the normal alkane n-C/sub 20/H/sub 42/
Journal Article
·
· J. Chem. Phys.; (United States)
OSTI ID:7360056
/sup 13/C NMR chemical shifts in a single crystal of n-eicosane (n-C/sub 20/H/sub 42/) have been measured using the method of high power proton decoupling and the chemical shift tensors were characterized. Principal values in ppM relative to CS/sub 2/ are: (a) For CH/sub 3/: sigma/sub 11/=166.7+-2,
- Research Organization:
- National Bureau of Standards, Washington, D.C. 20234
- OSTI ID:
- 7360056
- Journal Information:
- J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 64:2; ISSN JCPSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
EVEN-ODD NUCLEI
HYDROCARBONS
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ORGANIC COMPOUNDS
RESONANCE
STABLE ISOTOPES
TENSORS
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
EVEN-ODD NUCLEI
HYDROCARBONS
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUCLEI
ORGANIC COMPOUNDS
RESONANCE
STABLE ISOTOPES
TENSORS