Electronic spectra of crystals of dimolybdenum tetraformate and the tetrasulfatodimolybdenum(II) ion. [15/sup 0/K and 300/sup 0/K]

Journal Article · Wed Jul 21 00:00:00 EDT 1976 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00431a075· OSTI ID:7343385

Cotton, F A ^[1]; Martin, D S; Fanwick, P E; Peters, T J; Webb, T R

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1. Texas A and M Univ., College Station

Polarized absorption spectra on single crystals of Mo/sub 2/(O/sub 2/CH)/sub 4/ and K/sub 4/Mo/sub 2/(SO/sub 4/)/sub 4/ were used to study the electronic transitions. The spectra were presented and the results were compared with other quadruply bonded dimolybdenum systems. The characteristics and possible ..pi.. interactions of the carbonyl ligand group were also explored. (DDA)

• OSTI ID: 7343385
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 98:15; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ABSORPTION SPECTRA
CARBONYLS
CARBOXYLIC ACID SALTS
COMPLEXES
CRYSTALS
ENERGY-LEVEL TRANSITIONS
FORMATES
MOLYBDENUM COMPLEXES
MONOCRYSTALS
OXYGEN COMPOUNDS
SPECTRA
SULFATES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPLEXES
VERY LOW TEMPERATURE