Reactions of solid benzene with accelerated CH/sub 2//sup +/ ions. [Comparison with C/sup +/]
Journal Article
·
· J. Phys. Chem.; (United States)
Carbene (/sup 14/CH/sub 2//sup +/) ions, kinetic energy 10 eV, were impinged on solid benzene at -196/sup 0/C and the product yields determined. These were compared with the results obtained when bare carbon (/sup 14/C/sup +/) ions were used. In addition, the radioactivity distribution between the ring and the methyl group of the toluene product was established. Results support the earlier suggestion that carbene is an important intermediate in the benzene-to-toluene and benzene-to-cycloheptatriene syntheses. Surprisingly, labeled benzene was found to result from irradiating benzene with the /sup 14/CH/sub 2//sup +/ beam.
- Research Organization:
- Univ. of California, Berkeley
- OSTI ID:
- 7339464
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 80:17; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Irradiation of benzene with /sup 14/CH/sup +/ and /sup 14/CH/sub 3//sup +/ ions
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Journal Article
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Wed Mar 22 23:00:00 EST 1978
· J. Phys. Chem.; (United States)
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OSTI ID:7277557
THE CHEMICAL INTERACTION OF ACCELERATED CARBON-14 IONS WITH BENZENE (thesis)
Technical Report
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Mon Mar 13 23:00:00 EST 1961
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OSTI ID:4053924
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Journal Article
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Fri Oct 31 23:00:00 EST 1958
· Journal of Physical Chemistry (U.S.)
·
OSTI ID:4291603
Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600 -- Radiation Chemistry
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
ALKENES
AROMATICS
ATOMIC IONS
BEAMS
BENZENE
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CARBON 14
CARBON IONS
CARBON ISOTOPES
CHARGED PARTICLES
CHEMICAL REACTION YIELD
COLLISIONS
COMPARATIVE EVALUATIONS
CYCLOALKENES
ENERGY RANGE
EV RANGE
EV RANGE 01-10
EVEN-EVEN NUCLEI
HYDROCARBONS
ION BEAMS
ION COLLISIONS
IONS
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
LOW TEMPERATURE
NUCLEI
ORGANIC COMPOUNDS
RADIOISOTOPES
SOLIDS
TOLUENE
YEARS LIVING RADIOISOTOPES
YIELDS
400600 -- Radiation Chemistry
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
ALKENES
AROMATICS
ATOMIC IONS
BEAMS
BENZENE
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CARBON 14
CARBON IONS
CARBON ISOTOPES
CHARGED PARTICLES
CHEMICAL REACTION YIELD
COLLISIONS
COMPARATIVE EVALUATIONS
CYCLOALKENES
ENERGY RANGE
EV RANGE
EV RANGE 01-10
EVEN-EVEN NUCLEI
HYDROCARBONS
ION BEAMS
ION COLLISIONS
IONS
ISOTOPES
LABELLED COMPOUNDS
LIGHT NUCLEI
LOW TEMPERATURE
NUCLEI
ORGANIC COMPOUNDS
RADIOISOTOPES
SOLIDS
TOLUENE
YEARS LIVING RADIOISOTOPES
YIELDS