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Assigned lines of the A/sup 1/. sigma. /sup +/--X/sup 1/. sigma. /sup +/ bands of /sup 6/LiH, /sup 6/LiD, /sup 7/LiH, and /sup 7/LiD

Technical Report ·
DOI:https://doi.org/10.2172/7328463· OSTI ID:7328463

Tabulations are presented of the lines assigned to the A/sup 1/..sigma../sup +/--X/sup 1/..sigma../sup +/ transitions of the isotopic variants of lithium hydride. The /sup 7/LiD and most of the /sup 7/LiH lines are taken from the thesis of Jorgensen. The /sup 6/LiH, /sup 6/LiD and some of the /sup 7/LiH lines are taken from the thesis of Li and are a subset of the observed emission lines reported in companion reports. Spectral constant determinations from these lines and construction of improved Rydberg-Klein-Rees potential energy curves (including Born-Oppenheimer breakdown) is in progress. These spectra are now being compared with spectra obtained in this laboratory from collisions of fast (approximately 5 eV) H atoms with a Li/sub 2/ crossed beam.

Research Organization:
Iowa Univ., Iowa City (USA). Dept. of Chemistry
OSTI ID:
7328463
Report Number(s):
COO-2326-20
Country of Publication:
United States
Language:
English