Preparation and analytical applications of a propylenediaminetetraacetic acid resin

Journal Article · Mon Feb 28 23:00:00 EST 1977 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac50011a023· OSTI ID:7323622

Moyers, E M; Fritz, J S

A new chelating resin has been synthesized that contains a propylenediaminetetraacetic acid functional group which is attached to a carboxylic acid divinylbenzene resin via an esterification reaction. The new resin retains polyvalent metal cations at pH 3 or higher. It retains copper(II), uranium(VI), thorium(IV), and zirconium(IV) from more acidic solutions. A scheme is given for clean, rapid chromatographic separation of the last three elements from each other. The resin is also able to retain quantitatively a number of trace elements from simulated seawater.

• Research Organization: Ames Lab., IA
• OSTI ID: 7323622
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 49:3; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105 -- Separation Procedures
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ACTINIDES
ALKALINE EARTH METALS
BISMUTH
CADMIUM
CALCIUM
CARBOXYLIC ACIDS
CHELATING AGENTS
CHEMICAL ANALYSIS
CHEMICAL PREPARATION
CHROMATOGRAPHY
CHROMIUM
COBALT
COPPER
ELEMENTS
EXTRACTION APPARATUSES
EXTRACTION COLUMNS
HYDROGEN COMPOUNDS
INTERFERING ELEMENTS
IRON
MAGNESIUM
MANGANESE
METALS
NICKEL
ORES
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
PH VALUE
POLYMERS
QUALITATIVE CHEMICAL ANALYSIS
RESINS
SEAWATER
SEPARATION PROCESSES
SYNTHESIS
THORIUM
TRACE AMOUNTS
TRANSITION ELEMENTS
URANIUM
WATER
ZINC
ZIRCONIUM