Preparation and chromatographic applications of an amide resin

Journal Article · Tue Aug 01 00:00:00 EDT 1978 · Anal. Chem.; (United States)

DOI:https://doi.org/10.1021/ac50031a034· OSTI ID:6823350

Orf, G M; Fritz, J S

Synthetic routes are discussed for incorporation of a tertiary aliphatic amide group in a macroporous polystyrene--divinylbenzene resin. The amide resin retains uranium(VI), thorium(IV), and zirconium(IV) selectively from aqueous solution, pH 3.0. A liquid chromatographic separation scheme using the resin is given and quantitative results are obtained for uranium in synthetic and actual samples, and for thorium in synthetic samples. Gold(III) and palladium(II) are selectively retained by the resin from aqueous solutions containing hydrochloric acid. The resin has a capacity for gold of 1.7 mmol/g. 1 figure, 3 tables.

• Research Organization: Ames Lab., IA
• OSTI ID: 6823350
• Journal Information: Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 50:9; ISSN ANCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400102* -- Chemical & Spectral Procedures
400702 -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPOUNDS
ACTINIDES
ANIONS
AQUEOUS SOLUTIONS
CARNOTITE
CATIONS
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHROMATOGRAPHY
DISPERSIONS
DISSOLUTION
ELEMENTS
GOLD
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
IONS
LEACHING
LIQUID COLUMN CHROMATOGRAPHY
METALS
MINERALS
MIXTURES
ORGANIC COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PALLADIUM
PERCHLORIC ACID
PETROCHEMICALS
PETROLEUM PRODUCTS
PH VALUE
PLATINUM METALS
POLYMERS
QUANTITATIVE CHEMICAL ANALYSIS
RADIOACTIVE MATERIALS
RADIOACTIVE MINERALS
RESINS
SEPARATION PROCESSES
SOLUTIONS
SPECTRA
SULFURIC ACID
SYNTHESIS
THORIUM
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
URANINITES
URANIUM
URANIUM COMPOUNDS
URANIUM MINERALS
URANIUM VANADATES
VANADATES
VANADIUM COMPOUNDS
ZIRCONIUM