Thermochemistry and vapor pressure of aliphatic fluorocarbons. A comparison of the C-F and C-H thermochemical bond energies
The heat of formation of four organic fluorine compounds, including three completely fluorinated aliphatic compounds, was determined by a rotating-bomb method of combustion calorimetry. An earlier technique that used fused quartz ampoules for containing samples of volatile fluorine compounds was replaced by an improved technique that used sealed bags of a polyester film. For three of the compounds vapor pressure measurements were made by an improved method of comparative ebulliometry. The following values, in kcal. mole/sup -1/, are reported for the standard heat of formation, ..delta..Hf/sup 0//sub 296.16/, of these compounds from graphite and gaseous fluorine and hydrogen; m-fluorobenzotrifluoride(g), -184.17; perfluoromethylcyclohexane(g), -675.3; perfluoroethylcyclohexane(g), -769.7; and perfluoro-n-heptane(g), -789.0. These values were used with other thermochemical data to obtain a direct comparison of the C-F and C-H thermochemical bond energies in aliphatic compounds.
- Research Organization:
- Bureau of Mines, Bartlesville, OK
- OSTI ID:
- 7319833
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 63:7; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
BINDING ENERGY
CHEMICAL BONDS
ENERGY
ENTHALPY
FLUORINATED ALICYCLIC HYDROCARBONS
FLUORINATED ALIPHATIC HYDROCARBONS
FORMATION HEAT
HALOGENATED ALICYCLIC HYDROCARBONS
HALOGENATED ALIPHATIC HYDROCARBONS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
THERMODYNAMIC PROPERTIES
VAPOR PRESSURE