Purification and properties of ten organic sulfur compounds

Journal Article · Mon Mar 01 00:00:00 EST 1954 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j150513a022· OSTI ID:7319820

Haines, W E; Helm, R V; Bailey, C W; Ball, J S

Ten organic sulfur compounds, ethanethiol, 2-methyl-2-propanethiol, 1-pentanethiol, 2-thiabutane, 3-thiapentane, thiacyclobutane, thiacyclopentane, 2,3-dithiabutane, 3,4-dithiahexane and thiophene, were purified to at least 99.9 mole percent purity. The stability of the compounds under storage and distillation conditions was investigated. In addition to the boiling point and freezing point, the following properties were measured at 20, 25 and 30/sup 0/: density, viscosity, surface tension and refractive index for the r, C, D, e, v, F and g lines. Derived functions including refractivity intercept, specific dispersion, molecular refraction, parachor and molar volume were calculated and are discussed briefly. Mass, infrared and ultraviolet spectra were determined permitting some correlation of the effect of sulfur groupings on spectra.

• Research Organization: Bureau of Mines, Laramie, WY
• OSTI ID: 7319820
• Journal Information: J. Phys. Chem.; (United States), Vol. 58
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ORGANIC SULFUR COMPOUNDS
BOILING POINTS
DENSITY
MELTING POINTS
PURIFICATION
REFRACTIVITY
SURFACE TENSION
VISCOSITY
THIOLS
MEDIUM TEMPERATURE
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
SURFACE PROPERTIES
THERMODYNAMIC PROPERTIES
TRANSITION TEMPERATURE
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)