Purification and properties of ten organic sulfur compounds. Second series

Journal Article · Tue May 01 00:00:00 EDT 1956 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j150539a009· OSTI ID:7305374

Haines, W E; Helm, R V; Cook, G L; Ball, J S

Ten organic sulfur compounds, 2-propanethiol, 1-butanethiol, 2-butanethiol, 2-thiapropane, 2-thiapentane, 3-methyl-2-thiabutane, thiacyclohexane, 2-methylthiophene, 3-methylthiophene and benzo(b)thiophene, were purified to at least 99.9 mole percent purity. In addition to the boiling point, freezing point and cryoscopic constant, the following properties were measured at 20, 25 and 30/sup 0/: density, viscosity, surface tension and refractive index for the r, C, D, e, v, F, and g lines. Derived functions including refractivity intercept, specific dispersion, molecular refraction, parachor and molecular volume, were calculated. Mass, infrared and ultraviolet spectra were determined, permitting some correlation of the effect of sulfur groupings on spectra. The stability of the compounds under storage conditions was investigated.

• Research Organization: Bureau of Mines, Laramie, WY
• OSTI ID: 7305374
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 60:5; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
BOILING POINTS
DENSITY
MEDIUM TEMPERATURE
MELTING POINTS
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHYSICAL PROPERTIES
PURIFICATION
REFRACTIVITY
SURFACE PROPERTIES
SURFACE TENSION
THERMODYNAMIC PROPERTIES
THIOLS
TRANSITION TEMPERATURE
VISCOSITY