Mechanism of methanol synthesis from carbon dioxide and hydrogen. II. Selection of the reaction mechanism

Journal Article · Thu Mar 31 23:00:00 EST 1977 · Kinet. Catal. (USSR) (Engl. Transl.); (United States)

OSTI ID:7309136

Rozovskii, A Ya; Kagan, Yu B; Lin, G I; Slivinskii, E V; Loktev, S M; Liberov, L G; Bashkirov, A N

Possible mechanisms are discussed for the conversions of carbon dioxide and monoxide under conditions for the synthesis of methanol from carbon dioxide and hydrogen on an SNM-1 catalyst. Based on an analysis of the kinetic data the set of reactions occurring in the system at 170-260/sup 0/C and 50 atm are given. The reactions for CO/sub 2/ reduction into carbon monoxide and methanol do not have common steps.

• Research Organization: Inst. of Petrochemical Synthesis, Moscow
• OSTI ID: 7309136
• Journal Information: Kinet. Catal. (USSR) (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (USSR) (Engl. Transl.); (United States) Vol. 17:5; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

090221* -- Alcohol Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
ALCOHOLS
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROGEN
HYDROXY COMPOUNDS
KINETICS
METHANOL
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
SYNTHESIS