Perfluoropiperidine: entropy, heat of formation, and vapor pressure; N--F bond energy; and solid-state transitions
Conference
·
· J. Phys. Chem.; (United States)
OSTI ID:7305425
Measurements were made of the thermodynamic properties of perfluoropiperidine, C/sub 5/F/sub 11/N. The experimental studies provided the following information: values of heat capacity for the solid above 12/sup 0/K and the liquid below 320/sup 0/K; temperature of two transitions in the solid state; triple-point temperature; heats of transition, fusion, and vaporization; vapor pressure (302 to 355/sup 0/K); and the standard heats of combustion and formation at 298.15/sup 0/K. A value for the N--F thermochemical bond energy was calculated from the results.
- Research Organization:
- Bureau of Mines, Bartlesville, OK
- OSTI ID:
- 7305425
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 67; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMINES
AZINES
BINDING ENERGY
ENERGY
ENTHALPY
ENTROPY
FLUORINATED ALICYCLIC HYDROCARBONS
FORMATION HEAT
HALOGENATED ALICYCLIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHYSICAL PROPERTIES
PIPERIDINES
PYRIDINES
REACTION HEAT
THERMODYNAMIC PROPERTIES
TRANSITION TEMPERATURE
VAPOR PRESSURE
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
AMINES
AZINES
BINDING ENERGY
ENERGY
ENTHALPY
ENTROPY
FLUORINATED ALICYCLIC HYDROCARBONS
FORMATION HEAT
HALOGENATED ALICYCLIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHYSICAL PROPERTIES
PIPERIDINES
PYRIDINES
REACTION HEAT
THERMODYNAMIC PROPERTIES
TRANSITION TEMPERATURE
VAPOR PRESSURE