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Behavior of polymers in porous media

Conference ·
OSTI ID:7301321
Polyacrylamide (and the partially hydrolyzed form) and biopolysaccharide (produced by the plant pathogen Xanthomonas compestries) are compared for use in enhanced oil recovery. The viscosity imparted to a waterflood by polysaccharide is less reduced by mechanical degradation and increased salt concentration than is the case for the acrylamide thickened flood. Large amounts of the polyacrylamide are required for high permeability rock and a highly saline aqueous phase. The biopolymer degrades chemically at high temperatures. However, the thermal stability of the acrylamide is not established above 140/sup 0/F. The polyacrylamide has relatively long-term stability, unlike the biopolymer. This lack of long-term stability for the biopolymer is not entirely due to the presence of oxygen in the flood. Both polymers form gels under various conditions. Gel formation occurs if the biopolymer flood contains multivalent cations, comes in contact with alkaline minerals in the reservoir rock, and has the appropriate pH. The polyacrylamide flood forms gels or precipitates with certain organic cations and multivalent inorganic cations. It was noted that the transport properties of the biopolymer flood may be a function of pH.
OSTI ID:
7301321
Country of Publication:
United States
Language:
English

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