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U.S. Department of Energy
Office of Scientific and Technical Information

Method for waterflooding petroliferous strata

Patent ·
OSTI ID:7299548
A water-soluble, anionic or nonionic surfactant (e.g. ammonium petroleum sulfonate) plus a water-insoluble, oil-soluble, organic polar material such as an organic acid containing from 4 to 20 carbon atoms or an n-aliphatic alcohol containing from 6 to 12 carbon atoms (e.g. n-octanol) are employed in enhanced oil recovery. Both surfactant and alcohol may be injected together as one aqueous slug or the alcohol slug may be introduced into the reservoir ahead of the surfactant slug. Berea sandstone cores were saturated with 50,000 ppM sodium chloride solution, flooded with 80 pale oil (a solvent refined Mid-Continent lubricating oil with a viscosity of 80 S.S.U. at 100/sup 0/F), and then water-flooded before treatment with a slug of sulfonate and alcohol. The maximum recovery obtained was about 48 percent of residual oil after the waterflood. A field test was conducted in southern Oklahoma, following a waterflood, with a more dilute slug of sulfonate and alcohol. The reservoir was sandstone with an average porosity of 20.5 percent and an average air permeability of 125 md. The crude was approximately 36/sup 0/ API with a viscosity of 5 cp. A recovery of about 15 percent of residual crude was obtained.
Assignee:
Continental Oil Co.
Patent Number(s):
US 3366174
OSTI ID:
7299548
Country of Publication:
United States
Language:
English