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Title: Correlation of Mg/Fe partitioning between garnet and biotite with /sup 18/O//sup 16/O partitioning between quartz and magnetite

Journal Article · · Am. J. Sci.; (United States)

Isotopic and chemical data for thirteen metamorphic rocks containing garnet and biotite are used to investigate the dependence of the Mg--Fe partition upon temperature, expressed as the /sup 18/O//sup 16/O fractionation between quartz and magnetite, and upon chemical variation in both phases. Additional sets of samples considered to have equilibrated at nearly the same temperature are utilized to improve the least-squares solution of the compositional coefficients. The most acceptable least-squares solution, using the singular-value decomposition algorithm, is: K/sub D//sup Mg-Fe//sub G-B/ = -0.177(+-0.010)1000 ln/sub ..cap alpha..//sup Q//sub M/ - 1.22(+-0.14)X/sup G//sub Mn/ - 2.14(+- 0.13)X/sup G//sub Ca/ + 1.40(+- 0.09)X/sup B//sub Fe/ + 0.942(+- 0.109)X/sup B//sub Ti/ - 1.59(+- 0.21)X/sup B//sub Al/sup vi// - 0.492(+- 0.068). K/sub D/ is primarily dependent upon temperature but is also dependent upon compositional variation, particularly upon X/sup B//sub Fe/, although X/sup G//sub Ca/ becomes significant at higher concentrations.

Research Organization:
California Inst. of Tech., Pasadena
OSTI ID:
7284056
Journal Information:
Am. J. Sci.; (United States), Vol. 277:6
Country of Publication:
United States
Language:
English