Iron, magnesium, and titanium isotopic fractionations between garnet, ilmenite, f ayalite, biotite, and tourmaline: Results from NRIXS, ab initio, and study of mineral separates from the Moosilauke metapelite

Nie, Nicole X.; Dauphas, Nicolas; Alp, Esen E.; Zeng, Hao; Sio, Corliss K.; Hu, Justin J.; Chen, Xi; Aarons, Sarah M.; Zhang, Zhe; Bi, Wenli; Hu, Michael Y.; Zhao, Jiyong; Shahar, Anat; Roskosz, Mathieu; Teng, Fang-Zhen; Krawczynski, Michael J.; Heck, Philipp R.; Spear, Frank S.

doi:10.1016/j.gca.2021.03.014

Title: Iron, magnesium, and titanium isotopic fractionations between garnet, ilmenite, f ayalite, biotite, and tourmaline: Results from NRIXS, ab initio, and study of mineral separates from the Moosilauke metapelite

Journal Article · Tue Jun 01 00:00:00 EDT 2021 · Geochimica et Cosmochimica Acta

DOI:https://doi.org/10.1016/j.gca.2021.03.014· OSTI ID:1830018

Nie, Nicole X. ^[1]; Dauphas, Nicolas ^[2]; Alp, Esen E. ^[3]; Zeng, Hao ^[2]; Sio, Corliss K. ^[4]; Hu, Justin J. ^[2]; Chen, Xi ^[2]; Aarons, Sarah M. ^[5]; Zhang, Zhe ^[2]; Bi, Wenli ^[3]; Hu, Michael Y. ^[3]; Zhao, Jiyong ^[3]; Shahar, Anat ^[6]; Roskosz, Mathieu ^[7]; Teng, Fang-Zhen ^[8]; Krawczynski, Michael J. ^[9]; Heck, Philipp R. ^[10]; Spear, Frank S. ^[11]

Carnegie Inst. of Science, Washington, DC (United States); Univ. of Chicago, IL (United States). Enrico Fermi Inst.
Univ. of Chicago, IL (United States). Enrico Fermi Inst.
Argonne National Lab. (ANL), Argonne, IL (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Univ. of Chicago, IL (United States). Enrico Fermi Inst. ; Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography
Carnegie Inst. of Science, Washington, DC (United States)
Univ. Pierre et Marie Curie, Paris (France)
Univ. of Washington, Seattle, WA (United States)
Washington Univ., St. Louis, MO (United States)
Univ. of Chicago, IL (United States); The Field Museum of Natural History, Chicago, IL (United States)
Rensselaer Polytechnic Inst., Troy, NY (United States)

Interpreting isotopic signatures documented in natural rocks requires knowledge of equilibrium isotopic fractionation factors. Here, we determine equilibrium Fe isotope fractionation factors between several common rock-forming minerals using a comparative approach involving three independent methods: (i) isotopic analyses of natural minerals from a metapelite from Mt. Moosilauke, New Hampshire, for which equilibration temperature and pressure are well constrained to be near the aluminosilicate triple point (T ≃ 500 °C, P ≃ 4 kbar), (ii) Nuclear Resonant Inelastic X-ray Scattering (NRIXS) measurements of Fe force constants of minerals, and (iii) Density Functional Theory (DFT) ab initio calculations of Fe force constants of minerals. The minerals studied for Fe isotopes include, in increasing order of their β-factors: garnet < ilmenite ≈ fayalite < biotite < tourmaline < muscovite ≈ plagioclase. Some of this ordering is affected by the presence of Fe³⁺ in the minerals, which tends to form stiffer bonds and be associated with heavy Fe isotope enrichments relative to Fe²⁺. We are, however, able to assess the magnitude of the effect of the ratio Fe³⁺/ΣFe on equilibrium fractionation factors, notably on the ilmenite-hematite solid solution. Equilibrium Fe isotopic fractionation factors between garnet, ilmenite, biotite, tourmaline and fayalite are determined. We also report Mg and Ti isotopic compositions of selected Moosilauke minerals that allow us to better constrain the equilibrium fractionation factors for garnet-biotite-tourmaline (Mg isotopes) and biotite-ilmenite (Ti isotopes). We show how the newly determined equilibrium fractionation factors can be used to address diverse problems in Earth and planetary sciences, notably (i) Fe and Mg isotopic fractionation during anatexis, (ii) Fe isotopic fractionation in lunar ilmenite, and (iii) Ti isotopic fractionation during fluvial transport of minerals.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Aeronautics and Space Administration (NASA); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1830018

Journal Information:: Geochimica et Cosmochimica Acta, Vol. 302; ISSN 0016-7037

Publisher:: Elsevier; The Geochemical Society; The Meteoritical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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