Dipole moments and transition probabilities of the sup 3. Pi. sub g -- b sup 3. Sigma. sub u sup + , sup 3. Pi. sub u -- a sup 3. Sigma. sub g sup + , and sup 3. Pi. sub g -- c sup 3. Pi. sub u systems of molecular

Journal Article · Sat Feb 29 23:00:00 EST 1992 · Physical Review A. General Physics; (United States)

DOI:https://doi.org/10.1103/PhysRevA.45.2784· OSTI ID:7276891

Guberman, S L ^[1]; Dalgarno, A ^[2]

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1. Institute for Scientific Research, 33 Bedford Street, Lexington, Massachusetts 02173 (United States)
2. Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States)

{ital Ab} {ital initio} calculations using the Born-Oppenheimer approximation are described of the dipole moments of the {ital i} {sup 3}{Pi}{sub {ital g}--}{ital b} {sup 3}{Sigma}{sub {ital u}}{sup +}, {ital c} {sup 3}{Pi}{sub {ital u}--}{ital a} {sup 3}{Sigma}{sub {ital g}}{sup +}, and {ital i} {sup 3}{Pi}{sub {ital g}--}{ital c} {sup 3}{Pi}{sub {ital u}} transitions of molecular hydrogen. Tables are provided of the dipole transition probabilities and Franck-Condon factors. Franck-Condon factors are presented for transitions originating in the lowest vibrational level of the ground {ital X} {sup 1}{Sigma}{sub {ital g}}{sup +} state.

• OSTI ID: 7276891
• Journal Information: Physical Review A. General Physics; (United States), Journal Name: Physical Review A. General Physics; (United States) Vol. 45:5; ISSN 1050-2947; ISSN PLRAA
• Country of Publication: United States
• Language: English

Related Subjects

664200* -- Spectra of Atoms & Molecules & their Interactions with Photons-- (1992-)
74 ATOMIC AND MOLECULAR PHYSICS
BORN-OPPENHEIMER APPROXIMATION
DIPOLE MOMENTS
ELECTRONIC STRUCTURE
ELEMENTS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
FRANCK-CONDON PRINCIPLE
GROUND STATES
HYDROGEN
MOLECULES
NONMETALS
VIBRATIONAL STATES