Determination of dibutylbutylphosphonate in the presence of tributylphosphate by gas liquid chromatography

Conference · Sat May 01 04:00:00 EDT 1976

OSTI ID:7263814

Johnson, S J

A gas chromatographic determination of dibutylbutyl-phosphonate in the presence of tributylphosphate was developed. The separation was done on a 183 cm by 3 mm stainless steel column packed with 10 percent Carbowax 20M--TPA on 80/100 mesh Chromosorb W AW and detected by flame ionization. A nitrogen carrier gas flow of 40 cm/sup 3//min and an oven temperature of 180/sup 0/C produced optimum resolution and column efficiency. The use of temperature programming reduced retention times and thus analysis time. An internal standard of 10 percent v/v n-tridecane was added to all samples and standards.

• Research Organization: Atlantic Richfield Hanford Co., Richland, Wash. (USA)
• DOE Contract Number: E(45-1)-2130
• OSTI ID: 7263814
• Report Number(s): ARH-SA-249; CONF-760668-1
• Country of Publication: United States
• Language: English

Related Subjects

050800 -- Nuclear Fuels-- Spent Fuels Reprocessing
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
BUTYL PHOSPHATES
CHROMATOGRAPHY
ESTERS
GAS CHROMATOGRAPHY
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORIC ACID ESTERS
QUANTITY RATIO
SEPARATION PROCESSES
TBP
TEMPERATURE DEPENDENCE