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Control of nitric acid plant stack opacity during start-up and shutdown

Patent ·
OSTI ID:7256171
This patent describes an improvement in a process for the production of nitric acid wherein air and ammonia are mixed and combusted in an ammonia burner to produce an effluent containing nitrogen oxides. The effluent is cooled, condensed and separated into a liquid weak acid stream and gas stream. The liquid weak acid and vapor streams are fed into an absorber tower wherein they are countercurrently contacted with water to produce a nitric acid stream and an overhead with a reduced nitrogen oxides content. The overhead is combusted with a fuel in the presence of a catalyst in a catalytic combustor to produce a combustor exhaust, work expanded in an expander to recover energy and vented to the atmosphere as stack exhaust. The improvement involves controlling the opacity of the stack opacity during shutdown of the process.
Assignee:
Air Products and Chemicals, Inc., Allentown, PA
Patent Number(s):
US 4869890
Application Number:
PPN: US 7-177713A
OSTI ID:
7256171
Country of Publication:
United States
Language:
English