Reactivity of anionic zirconaoxiranes toward metal carbonyls. Implications for the mechanism of homogeneously catalyzed carbon monoxide hydrogenation
Journal Article
·
· Organometallics; (United States)
- Univ. of Delaware, Newark, DE (United States)
Reactions of anionic zirconocene [eta][sup 2]-aldehyde complexes with metal carbonyls lead to rapid and quantitative formation of heterobimetallic complexes containing a new carbon-carbon bond, thereby suggesting a modified mechanism for homogeneously catalyzed carbon monoxide hydrogenation. Nine new bimetallic complexes are reported, including the X-ray structure of ([eta][sup 5]-C[sub 5]H[sub 4]Me)[sub 2]Zr(Me)[OCH(C[sub 6]H[sub 4]Me)C(O)Fe (CO)[sub 4]]Li-(THF)[sub 2]. 13 refs., 1 fig.
- OSTI ID:
- 7242971
- Journal Information:
- Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 13:6; ISSN 0276-7333; ISSN ORGND7
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6745181
Synthesis and characterization of Cp{sub 2}Zr(CH(Me)(6-ethylpyrid-2-yl)) (CO){sup +}, a d{sup 0} metal alkyl carbonyl complex. Coordination chemistry of the four-membered azazirconacycle Cp{sub 2}Zr({eta}{sup 2}-C,N-CH(Me)(6-ethylpyrid-2-yl)){sup +}
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Related Subjects
10 SYNTHETIC FUELS
102000 -- Synthetic Fuels-- Products & By-Products-- (1990-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
FLUIDS
GASES
HYDROGENATION
IRON COMPLEXES
LITHIUM COMPLEXES
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SCATTERING
SYNTHESIS GAS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
ZIRCONIUM COMPLEXES
102000 -- Synthetic Fuels-- Products & By-Products-- (1990-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSIS
CHALCOGENIDES
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
DIFFRACTION
FLUIDS
GASES
HYDROGENATION
IRON COMPLEXES
LITHIUM COMPLEXES
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SCATTERING
SYNTHESIS GAS
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
ZIRCONIUM COMPLEXES