Selective transformation of carbonyl ligands to organic molecules. Progress report, September 1, 1984-August 31, 1985
Progress report for this reporting period covers: (1) carbon monoxide fixation and synthesis reactions which includes C/sub 2/-C/sub 3/ oxygenated ligands and carbohydrate chemistry; (2) eta/sup 5//eta/sup 3/-indenyl tautomerization in promoting coordinated ligand reactions; (3) bimetallic activation of coordinated ligands which covers bimetallic eta (eta/sup 1/-C,O) acetyl complexes and bimetallic ..mu..-(eta/sup 2/-C,O) acetyl complexes. Some of the accomplishments include the following: incorporation of two carbonyls into the C/sub 2/-carbalkoxymethyl Fe complexes; conversion of the carbomethoxymethyl ligand on FpCH/sub 2/CO/sub 2/Me into the C/sub 3/ organic dimethyl malonate; investigation of synthesis reactions on transition organometallic complexes that incorporate CO ligands into a growing alkoxymethylene chain; and synthesis of Fe-Zr and Fe-W bimetallic u-(eta/sup 1/-C,O) acetyl complexes.
- Research Organization:
- Rensselaer Polytechnic Inst., Troy, NY (USA)
- DOE Contract Number:
- AC02-82ER13022
- OSTI ID:
- 5716465
- Report Number(s):
- DOE/ER/13022-1; ON: DE85011919
- Country of Publication:
- United States
- Language:
- English
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Selective transformation of carbonyl ligands to organic molecules: Progress report for period September 1, 1982-August 31, 1983
Photochemistry of (eta/sup 5/-indenyl)/sub 2/Fe/sub 2/(CO)/sub 4/ in the presence of 2e/sup -/ donor ligands: reversible formation of the radicals (indenyl)Fe(CO)/sub 2/L
Related Subjects
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBOHYDRATES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLATION
CARBONYLS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
IRON COMPLEXES
ISOMERIZATION
LIGANDS
MOLYBDENUM COMPLEXES
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES
ZIRCONIUM COMPLEXES