Selective transformation of carbonyl ligands to organic molecules. Progress report, September 1, 1983-August 31, 1986
Ongoing synthetic and mechanistic transition organometallic chemistry studies in my research group focus on selectively converting ligated carbon monoxide into C/sub 2/-C/sub 4/ oxygenated organics. In particular, we are establishing viable coordinated ligand reactions for CO reduction and subsequent synthesis reactions (i.e., chain growth of the C/sub 1/ ligand by incorporating CO). Results obtained in these stoichiometric studies using fully characterized organometallic complexes then will be extended to more labile (and potentially catalytic) organometallic systems. The following sections detail the results of our DOE supported research during the period 9/1/83-8/31/86, on carbon monoxide fixation and synthesis reactions, and organometallic Lewis acids - bimetallic activation of coordinated ligands. 62 refs., 19 figs.
- Research Organization:
- Rensselaer Polytechnic Inst., Troy, NY (USA)
- DOE Contract Number:
- AC02-82ER13022
- OSTI ID:
- 5827253
- Report Number(s):
- DOE/ER/13022-3; ON: DE86009965
- Country of Publication:
- United States
- Language:
- English
Similar Records
Selective transformation of carbonyl ligands to organic molecules: Progress report for period September 1, 1982-August 31, 1983
Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Final report, April 1, 1977-June 30, 1984
Related Subjects
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CARBOHYDRATES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLATION
CARBONYLS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
IRON COMPLEXES
ISOMERIZATION
KETENES
LIGANDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES