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Iterative sequence for phase equilibrium calculations incorporating the Redlich--Kwong equation of state

Conference ·
OSTI ID:7223692
Phase equilibria equations which incorporate the Redlich-Kwong equation of state are nonlinear and therefore must be solved by an iterative method. The method of successive substitutions is commonly employed. This method, however, almost always diverges for bubble point, dew point, and two-phase calculations in the vicinity of the critical. Iterative methods which converge for these calculations are presented in this paper. The iterative methods are entitled ''minimum variable Newton-Raphson'' (MVNR) methods, since they attempt to minimize the number of variables for which simultaneous iteration is required, and they use the Newton-Raphson method for the correction step. Procedures are given for obtaining starting values for the first iteration. Several example problems are discussed.
OSTI ID:
7223692
Report Number(s):
CONF-761008-59
Country of Publication:
United States
Language:
English

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