Liquid--vapor frequency shifts and torsional frequencies in far infrared spectra

Journal Article · Sat May 01 00:00:00 EDT 1965 · J. Mol. Spectrosc.; (United States)

DOI:https://doi.org/10.1016/0022-2852(65)90091-3· OSTI ID:7219959

Crowder, G A ^[1]; Scott, D W

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1. Oklahoma State Univ., Stillwater

Shifts of low frequencies (wave numbers less than 250 cm/sup -1/) between liquid (or solution) and vapor states were observed in the far infrared spectra of a variety of compounds. Frequencies for hindered internal rotation of 2,3-dithiabutane and 2-propanethiol and hindered pseudo-rotation of thiacyclopentane were found to agree well with conclusions based on calorimetric data for the compounds.

• OSTI ID: 7219959
• Journal Information: J. Mol. Spectrosc.; (United States), Vol. 16:1
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
FLUORINATED AROMATIC HYDROCARBONS
INFRARED SPECTRA
ORGANIC SULFUR COMPOUNDS
PYRIDINES
PYRROLES
THIOLS
HETEROCYCLIC COMPOUNDS
LIQUIDS
VAPORS
AROMATICS
AZINES
AZOLES
FLUIDS
GASES
HALOGENATED AROMATIC HYDROCARBONS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)