Heats of combustion, formation, and isomerization of the seven isomeric C/sub 4/H/sub 10/S alkane thiols and sulfides

Journal Article · Thu May 01 00:00:00 EDT 1958 · J. Phys. Chem.; (United States)

DOI:https://doi.org/10.1021/j150563a024· OSTI ID:7219948

Hubbard, W N; Good, W D; Waddington, G

The heat of combustion of each of the seven C/sub 4/H/sub 10/S isomers--1-butanethiol, 2-butanethiol, 2-methyl-1-propanethiol, 2-methyl-2-propanethiol, 2-thiapentane, 3-thiapentane and 3-methyl-2-thiabutane--was determined in a rotating-bomb calorimeter. The combustion and calibration experiments were performed in a single unified series. The results supplemented by experimental values of the heat of vaporization of each compound and the heat of formation of H/sub 2/SO/sub 4/ . 7OH/sub 2/O from rhombic sulfur, oxygen and water, gave values of the standard heat of formation and standard heat of isomerization at 25/sup 0/ for each compound in the liquid and gaseous states.

• Research Organization: Bureau of Mines, Bartlesville, OK
• OSTI ID: 7219948
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 62:5; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
CHEMICAL REACTIONS
COMBUSTION HEAT
ENERGY
ENTHALPY
FLUIDS
FORMATION HEAT
GASES
HEAT
ISOMERIZATION
LIQUIDS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
THERMODYNAMIC PROPERTIES
THIOLS
TRANSITION HEAT
VAPORIZATION HEAT