High-performance batteries for stationary energy storage and electric-vehicle propulsion. Progress report, October--December 1976. [Li--Al/LiCl--KCl/FeS or FeS/sub 2/, operate at 400 to 450 C]

Technical Report · Fri Apr 01 04:00:00 EST 1977

DOI:https://doi.org/10.2172/7215284· OSTI ID:7215284

Nelson, P. A.; Yao, N. P.; Steunenberg, R. K.; Chilenskas, A. A.; Gay, E. C.; Battles, J. E.; Hornstra, F.; Miller, W. E.; Roche, M. F.; Shimotake, H.

These batteries are being developed for electric vehicle propulsion and for stationary energy storage applications. The present battery cells, which operate at 400 to 450/sup 0/C, are of a vertically oriented, prismatic design with a central positive electrode of FeS or FeS/sub 2/, two facing negative electrodes of lithium--aluminum alloy, and an electrolyte of molten LiCl--KCl. Testing and evaluation of industrially fabricated cells is continuing. During this period, Li--Al/FeS and Li--Al/FeS/sub 2/ cells from Eagle-Picher Industries were tested, and tests of Li--Al/FeS cells from Gould Inc. were initiated. The cells are tested individually and in parallel and series battery configurations. These tests provide information on the effects of cell design modifications and alternative materials. Improved electrode and cell designs are being developed and tested at ANL, and the more promising designs are incorporated in the industrially fabricated cells. Among the concepts receiving major attention are carbon-bonded positive electrodes, scaled-up stationary energy storage cell designs, additives to extend electrode lifetime, and alternative electrode separators. The materials development efforts include the development of a new lightweight electrical feedthrough; investigations of new separator materials (e.g.,Y/sub 2/O/sub 3/ powder, Y/sub 2/O/sub 3/ felt, and porous, rigid ceramics); corrosion tests of materials for cell components; and postoperative examinations of cells. The cell chemistry studies were directed to discharge mechanisms of FeS electrodes, emf measurements of the LiAl/FeS/sub 2/ couple at various states of discharge, and studies of other transition-metal sulfides as positive-electrode materials. The advanced battery effort mainly concerned the use of calcium alloys for negative electrode and transition metal sulfides or oxides for the positive electrode. 13 figures, 18 tables.

• Research Organization: Argonne National Lab., IL (USA)
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 7215284
• Report Number(s): ANL-77-17
• Country of Publication: United States
• Language: English

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25 ENERGY STORAGE
250901* -- Energy Storage-- Batteries-- Design & Development
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