Electrochemical investigation of complexes of Ni(II) with diphenylphosphine

Journal Article · Sat Jun 01 00:00:00 EDT 1985 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7202426

Popod'ko, N R; Kaverin, V V; Pozdeeva, A A; Reznik, L B; Yur'ev, V P; Zhdanov, S I

By electrochemical methods it was shown that the products of the reactions of Ni(acac)2 and NiBr2 with diphenylphosphine contain two Ni-P bonds which are broken on reduction with the formation of a cluster and diphenylphosphine. It was shown that diphenylphosphine can undergo catalytic discharge on mercury with the participation of tetrabutylammonium cations. The electrochemical methods enabled the authors to distinguish unambiguously nickel phosphide complexes and Ni(PPh/sub 2/H)/sub 4/.

• Research Organization: Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa
• OSTI ID: 7202426
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 54:12, PT 2; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400* -- Electrochemistry
ALKENES
BROMIDES
BROMINE COMPOUNDS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DIAGRAMS
DISPERSIONS
ELECTROCHEMISTRY
ELECTROLYTES
ELEMENTS
ESTERS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
KINETICS
MERCURY
METALS
MIXTURES
NICKEL BROMIDES
NICKEL COMPLEXES
NICKEL COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHINIC ACID ESTERS
POLAROGRAPHY
POTENTIOMETRY
QUANTITATIVE CHEMICAL ANALYSIS
QUANTITY RATIO
REACTION KINETICS
REDUCTION
SOLUTIONS
SYNTHESIS
TITRATION
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS