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Synthesis and catalytic activity of ruthenium(II) complexes containing acetylacetonate

Journal Article · · Journal of Coordination Chemistry
; ;  [1]
  1. North-Eastern Hill Univ., Shillong (India)

Synthesis and characterisation of complexes of ruthenium(II), [RuBr(acac)L{sub 2}]{sub 2} (L = PPh{sub 3}, AsPh{sub 3}, py; L{sub 2} = bipy or phen) and M{sub 2}[RuBr{sub 3}(acac)] (M = Me{sub 4}N, Cs or Rb) are described. Catalytic oxidations of PPh{sub 3} and AsPh{sub 3} using [RuBr(acac)(PPh{sub 3}){sub 2}]{sub 2} and [RuBr(acac)(AsPh{sub 3}){sub 2}]{sub 2} have been carried out by molecular oxygen. 13 refs., 1 fig., 3 tabs.

Sponsoring Organization:
USDOE
OSTI ID:
508209
Journal Information:
Journal of Coordination Chemistry, Journal Name: Journal of Coordination Chemistry Journal Issue: 4 Vol. 36; ISSN JCCMBQ; ISSN 0095-8972
Country of Publication:
United States
Language:
English

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