Reactions of chemical warfare agents with DS2: Product identification by NMR. 1. Organophosphorus compounds. Final report, Feb 89-Dec 90

Technical Report · Mon Jun 01 00:00:00 EDT 1992

OSTI ID:7200679

Beaudry, W T; Szafraniec, L L; Ralph, L D

Multinuclear NMR (31P and 13C) was used to monitor the reactions--of GA, GB, GD, VX, and O,S-diethyl methylphosphonothiolate (DEMPS) with DS2. The organophosphorus products from the primary and secondary reactions in DS2 were identified. Variations in the reaction profiles as a function of time and added water provided valuable insight into the mechanism of action of DS2 and the important factors influencing its effectiveness. It was found that low concentrations of water (5%) had no measurable effect on the efficacy of DS2 to decontaminate the agents. However, at higher concentrations of water (50%), the nonaqueous chemistry of DS2 was destroyed and hydrolysis behavior predominated.

• Research Organization: Chemical Research, Development and Engineering Center, Aberdeen Proving Ground, MD (United States)
• OSTI ID: 7200679
• Report Number(s): AD-A-254284/3/XAB; CRDEC-TR-364
• Country of Publication: United States
• Language: English

Related Subjects

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEFENSE
CHEMICAL WARFARE AGENTS
DECONTAMINATION
BEHAVIOR
CHEMICAL REACTIONS
CHEMISTRY
DEUTERIUM COMPOUNDS
FUNCTIONS
HYDROLYSIS
MONITORS
NUCLEAR MAGNETIC RESONANCE
ORGANIC PHOSPHORUS COMPOUNDS
SULFUR COMPOUNDS
VARIATIONS
WATER
CLEANING
DECOMPOSITION
HYDROGEN COMPOUNDS
LYSIS
MAGNETIC RESONANCE
MEASURING INSTRUMENTS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
RESONANCE
SOLVOLYSIS
WEAPONS
450600* - Military Technology
Weaponry
& National Defense- Chemical & Biological- (1990)