Reaction of organic complexes of chromium, molybdenum, and tungsten with cis-. cap alpha. ,. beta. -dinitrostilbene

Journal Article · Fri Sep 20 04:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00947737· OSTI ID:7194550

Todres, Z V; Dyusengaliev, K I

The authors discuss the reaction of weak ..pi..-acids, such ascis-a, b-dinitrostilbene (cis-DNS) and cis-a-nitrostilbene (cis-NS), with organometallic complexes (OMC) (I) - (VII) of the general formula (CO)/sub 4/ML/sub 2/. In all cases studied, no changes were observed in the CO group bands in the IR spectra of the mixtures or chemical shifts in the corrosponding H 1 and C 13 NMR spectra. However, there is some reaction of OMC with cis-DNS, or a cis-trans-isomerization of the olefinic compounds is observed.

• Research Organization: A.N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences, Moscow
• OSTI ID: 7194550
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:3,PT.2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AROMATICS
BINDING ENERGY
CARBON 13
CARBON ISOTOPES
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHROMIUM COMPLEXES
COMPLEXES
COMPLEXOMETRY
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
EVEN-ODD NUCLEI
FERMIONS
HYDROCARBONS
HYDROGEN 1
HYDROGEN ISOTOPES
INFRARED SPECTRA
ISOMERIZATION
ISOTOPES
LEPTONS
LIGHT NUCLEI
MOLYBDENUM COMPLEXES
NITRO COMPOUNDS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
STILBENE
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES
VALENCE