Reaction of nitrostilbenes with uranocene and its derivatives

Journal Article · Fri Dec 20 04:00:00 EST 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00956107· OSTI ID:7150993

Todres, Z V; Dyusengaliev, K I; Sevast'yanov, V G

The authors study the reaction of dibutyluranocene with 4-nitrostilbene (4-NS) which may be considered a nitrobenzene having a styryl substituent at C-4. In order to study the effect of alkyl substituents in the uranocene molecule on the observed cis-trans isomerization of nitrostilbenes, the authors examined uranocene without substituents ( (dicyclooctatetraene)uranium and didecyluranocene 1,1'-di (decylcyclooctatetraene)-uranium). The authors found that the introduction of two n-butyl groups into uranocene leads to a decrease in the isomerization, while the introduction of two n-decyl groups leads to the complete disappearance of this process.

• Research Organization: A.N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences, Moscow
• OSTI ID: 7150993
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:6,PT.2; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTINIDE COMPLEXES
ACTINIDE COMPOUNDS
AROMATICS
BINDING ENERGY
CHALCOGENIDES
CHARGE EXCHANGE
CHEMICAL COMPOSITION
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
COMPLEXOMETRY
ENERGY
HYDROCARBONS
ISOMERIZATION
ISOMERS
KINETICS
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
STILBENE
STRUCTURAL CHEMICAL ANALYSIS
URANIUM COMPLEXES
URANIUM COMPOUNDS
URANIUM DIOXIDE
URANIUM OXIDES
VALENCE